Product ID:FORMULA 197 CARB
MSDS Date:02/01/1987
FSC:6850
NIIN:00N010499
MSDS Number: BHNSW

STATE CHEMICAL MANUFACTURING COMPANY

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

CRESOL, ALL ISOMERS (CRESYLIC ACID) (SARA III)

CAS: 1319-77-3

RTECS: GO5950000

Fraction By Weight: <12%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: <10%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

O-DICHLOROBENZENE (SARA III)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: <15%

OSHA PEL C 50 PPM

ACGIH TLV: S, 25PPM/50 STEL9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: >60%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-DICHLOROBENZENE (1,4-DICHLOROBENZENE) (SARA III)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: <15%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM,A3 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <10%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NIOSH STUDIES INDICATE 2-BUTOXYETHANOL
HAS CAUSED REPRO DISORDERS IN LAB ANIM (RATS/MICE) & MAY DO THE
SAME IN HUMANS .INGEST:POSS BLINDNESS/DEATH.POSS CARD SENSIT
LEADING TO VENTRICULAR FIBRILL ATION.CHRONIC INHAL/SKIN
ABSORPTION:POSS SYSTEMIC METHANOL POISONING.CHRONIC INHAL:POSS
KIDNEY,LIVER,NERV SYS DMG.
Explanation of Carcinogenicity:DICHLOROMETHANE:INADEQ EVID FOR CARC IN
HUM,SUFF IN ANIM (IARC 1987);ACGIH A2=SUSP HUM CARC (1989). (SEE
SUPP DATA)
Effects of Overexposure:EYES/SKIN:SEV BURNS.INGEST:POSS
FATAL,BLINDNESS,SEV BURNS.INHAL:SEV BURNS.VAP HARMFUL.INHAL OF
DICHLOROBENZENE AT >75 PPM:POSS CNS DEPRESSION
(HDCH,DIZZ,NAUS,DRUNKENESS,UNCON,DEATH).P-DICHLOROBENZENE: POSS
MENTAL CONFUSION,FATIGUE,LOSS OF
APPETITE,NAUSEA,VOMITING,COUGH,LOSS OF SENSE OF BALANCE & VISUAL
DISTURBANCES.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ LOTS OF COOL H*2O FOR AT LEAST 15 MIN.GET
IMMED MED ATTN.SKIN:IMMED REMOVE CONTAM CLTHG & WASH W/ LOTS OF
SOAP & H*2O.IF IRRIT PERSISTS,GET MD.INGEST:CALL MD OR POISON
CONTROL CENT ER IMMED.IF CONSC,INDUCE VOMIT BY PUTTING FINGER DOWN
THROAT OR FOLLOW DIRECTIONS ON SYRUP OF IPECAC BOTTLE.INHAL:REMOVE
TO FRESH AIR.IF SYMP PERSIST,GET MD.AVOID EPINEPHRINE & SIMILAR
ACTING DRUGS.

Flash Point Method:TCC
Flash Point:129F,53.89C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:FOAM,CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .WATER MAY BE INEFFECTIVE DUE TO THE SOLVENT NATURE OF
THIS PRODUCT.
Unusual Fire/Explosion Hazard:CAUTION:COMBUSTIBLE.BURNING OF THIS
PRODUCT MAY CAUSE FORMATION OF HYDROGEN
CHLORIDE,PHOSGENE,CHLORINE,CARBON MONOXIDE OR CARBON DIOXIDE.

Spill Release Procedures:REMOVE ALL SOURCES OF HEAT,SPARKS OR OPEN
FLAME.VENTILATE AREA.ABSORB SPILL ON STATE OIL ABSORBENT,SAND OR
VERMICULITE.FLUSH REMAINING RESIDUE WITH DETERGENT & WATER.DO NOT
CONTAMINATE WATER SUPPLIES.
Neutralizing Agent:N/K

Handling and Storage Precautions:AVOID ALL CONT.USE W/ ADEQ
VENT.COMBUST.KEEP CONTRS CLSD WHEN NOT IN USE.DO NOT STORE
>100F,38C.DO NOT DROP.TOX TO FISH.KEEP OUT OF LAKES,STREAMS.
Other Precautions:NO SMKG IN AREA.DO NOT USE IN GENERAL VICIN OF ARC
WELDING,OPEN FLAMES OR HOT SURFACES.HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE .HEAT CAUSES PRESS BUILDUP.DO NOT
DILUTE.DO NOT USE VAP FOR DEGREASING.DO NOT (SEE SUPP DAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:VITON
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:AN IMPERVIOUS APRON IS OPTIONAL.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING,DRINKING OR SMOKING.
Supplemental Safety and Health
OTHER PREC:REUSE DRUMS.FOLLOW ALL LABEL DIRECTIONS & PREC BEFORE
USE.FOR INDUS & INSTITUTIONAL USE ONLY.NOT INTENDED FOR HOUSEHOLD
USE OR RESALE.KEEP OUT OF THE REACH OF CHILDREN.% VOLATILES BY
WT:85. EXPLAN OF CARCIN:P-DICHLOROBENZENE:INADEQ EVID FOR CARCIN IN
HUM,SUFF EVID FOR CARCIN IN ANIMALS (IARC 1987).

Boiling Pt:B.P. Text:103-212F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:1.127 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER,TWO LAYER LIQUID WITH A PHENOLIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,STRONG CAUSTICS OR CHEMICALLY ACTIVE LIGHT METALS.MAY
ADVERSELY AFFECT SOME PLASTICS.
Stability Condition to Avoid:EXPOSURE TO HEAT,SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING MAY RESULT IN THE FORMATION OF
HYDROGEN CHLORIDE,PHOSGENE,CHLORINE,CARBON MONOXIDE OR CARBON
DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IAW FEDERAL,STATE & LOCAL
REGULATIONS .OPEN DUMPING PROHIBITED.DESTROY EMPTY CONTRS BY
CRUSHING OR PERFORATING,OR GIVE TO DRUM RECONDITIONER FOR
RECYCLING.THIS PRODUCT SHOULD BE HANDLED AS RCRA HAZ WASTE IF
DISPOSAL REQUIRED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.